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Energy-saving butadiene production technology

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Ruihua's technology for butadiene production by oxygen-enriched dehydrogenation of butenes uses different feeding methods and different feed compositions to solve the blockage of the second-stage reactor of the traditional oxidative dehydrogenation process and extend the catalyst operation cycle. Due to the change of the feed composition, the energy consumption of the entire device is greatly reduced.
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Changzhou Ruihua Chemical has accumulated more than ten years of experience in ethylbenzene/styrene industrial engineering design, and successfully developed a complete set of ethylbenzene/styrene process technology at the beginning of the company's establishment. After nearly 10 years of technological improvement, the technology package has reached the leading level in all evaluation indicators in the latest equipment currently in operation.
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Propylene oxide is the third largest propylene derivative after polypropylene and acrylonitrile. It is mainly used in the production of polyether and propylene glycol. Its derivatives are widely used in industries such as automobiles, construction, food, tobacco, medicine and cosmetics. . Nearly 100 kinds of downstream products have been produced, which are important raw materials for fine chemical products.
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Up to now, some domestic devices in China have applied the technology of producing ethylbenzene/styrene from dry gas, mainly those with an annual output of 60,000 to 80,000 tons of styrene, which are distributed in PetroChina, Sinopec, ChemChina and various private enterprises. The dry gas method was used as a raw material to produce ethylbenzene, which solved the problem of dry gas resource utilization at that time. However, in the actual production for many years, the load of most of the dry gas to ethylbenzene/styrene equipment cannot reach the design value, let alone increase the production capacity to increase the efficiency when the price of styrene rises.
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The process of separating p-xylene by crystallization is an older process still in use. Before the emergence of adsorption separation technology, the separation of p-xylene by crystallization was the only technology for refining p-xylene. Due to the development of adsorption technology, the existing crystallization technology for the separation of mixed xylenes for equilibrium components no longer has advantages, but the separation of mixed xylenes for high-concentration p-xylene is still attractive.
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Maleic anhydride is one of the three major acid anhydride raw materials in the world (acetic anhydride, maleic anhydride, phthalic anhydride), and its downstream products have a wide range of development and application prospects, which can be used in synthetic resins, coatings, pesticides, lubricant additives, medicine, and paper Treatment agents, food additives, stabilizers, etc.
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Ruihua C4 cracking unit is transformed into methanol to propylene production technology, which can be used to produce propylene, ethylene, liquefied petroleum gas and aromatic gasoline. This technology is highly adaptable to the market, and the product scheme can be adjusted according to demand, and it is very competitive in small and medium-sized industrial applications.
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Succinic anhydride is a widely used organic chemical raw material. It can be used to produce vitamins, antibiotics; plant growth inhibitors, chemical intermediates and additives. It can also produce cross-linking agents, light stabilizers, and ultraviolet absorbers for polymer compounds; prepare alkyd resins, anthraquinone dyes, reinforcing fibers, and so on.
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1000
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Butadiene ranks second only to ethylene and propylene in petrochemical olefin raw materials. Butadiene is the main raw material for the production of synthetic rubber (styrene butadiene rubber, butadiene rubber, nitrile rubber, and neoprene). With the development of styrene plastics, copolymerization of styrene and butadiene is used to produce various resins with a wide range of uses (such as ABS resin, SBS resin, BS resin, MBS resin), making butadiene increasingly important in resin production status. In addition, butadiene is still used to produce 1,4-butanediol (engineering plastics), dinitrile (nylon 66 monomer), sulfolane, tetrahydrofuran, etc., so it is also an important basic chemical raw material.
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1000
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1000
Keywords:
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Double tube plate is a relatively common structure in heat exchangers in recent years. In order to avoid mixing of the two media in the tube side and the shell side to cause the material to be scrapped or cause a major accident, the double tube plate structure is generally adopted. During the hydraulic test of the equipment, the inner tube sheet leaked, which was difficult to rework, which would cause the equipment to be reworked. Therefore, the difficulty in manufacturing the heat exchanger with this structure was mainly the expansion of the inner tube sheet. If there is no experience in expansion of the same material and specification, expansion simulation test should be done to determine the expansion parameters.
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Keywords:
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Keywords:
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1000
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1000

Energy-saving butadiene production technology

Butadiene ranks second only to ethylene and propylene in petrochemical olefin raw materials. Butadiene is the main raw material for the production of synthetic rubber (styrene butadiene rubber, butadiene rubber, nitrile rubber, and neoprene). With the development of styrene plastics, copolymerization of styrene and butadiene is used to produce various resins with a wide range of uses (such as ABS resin, SBS resin, BS resin, MBS resin), making butadiene increasingly important in resin production status. In addition, butadiene is still used to produce 1,4-butanediol (engineering plastics), dinitrile (nylon 66 monomer), sulfolane, tetrahydrofuran, etc., so it is also an important basic chemical raw material.
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Butadiene ranks second only to ethylene and propylene in petrochemical olefin raw materials. Butadiene is the main raw material for the production of synthetic rubber (styrene butadiene rubber, butadiene rubber, nitrile rubber, and neoprene). With the development of styrene plastics, copolymerization of styrene and butadiene is used to produce various resins with a wide range of uses (such as ABS resin, SBS resin, BS resin, MBS resin), making butadiene increasingly important in resin production status. In addition, butadiene is still used to produce 1,4-butanediol (engineering plastics), dinitrile (nylon 66 monomer), sulfolane, tetrahydrofuran, etc., so it is also an important basic chemical raw material.

This technology is used for the oxidative dehydrogenation of butene to produce butadiene. In the entire process, a series of energy-saving technologies are applied to ensure high conversion rate and high selectivity, while greatly reducing production energy consumption.

 

Process flow

This technology adopts a multi-stage adiabatic fixed-bed reactor process, uses waste heat boilers between the stages, and uses combined equipment such as feed and discharge heat exchangers, post heat exchangers and compression heat pumps to save energy in the process of butadiene oxidative dehydrogenation to butadiene .

Ruihua Chemical also uses a special feed distribution method to feed oxygen-containing gas, butene and water vapor into each stage of the reactor according to a certain ratio. The product selectivity and catalyst life can be greatly improved.

 

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In addition, Ruihua Chemical has developed a catalyst that is more suitable for butene oxidative dehydrogenation, which has been verified to meet the requirements of oxidative dehydrogenation and has excellent process indicators.

 

Technical advantages

The feed temperature of butene oxidative dehydrogenation is 315~400℃, and the output temperature is 420℃~500℃. This process adopts the method of taking heat between sections to control the feed temperature of the reactor in the latter section, and generate medium-pressure steam for recovery. And compression heat pump technology is used in the process, which is different from the commonly used refrigerant heat pump technology. Its efficiency is 50~90%. The low-level energy heat source in this heat pump recovery system is used to generate low-pressure steam, which is incorporated into the system's steam pipe network.

● Proper oxygen-to-ene ratio and mild reaction conditions reduce the chance of carbon formation in the system, extend the life of the catalyst, and increase product selectivity.

● The butene and water vapor are fully fed at one time, and the air enters the reaction system separately, and the reaction is gentle, so the water to ene ratio can be reduced to about 8.

● With the application of energy-saving technology, the device has a significant energy-saving effect. The steam by-produced in the reaction stage can produce considerable economic benefits.

● For high-power electrical equipment, choosing a suitable turbine drive mode will also make a greater contribution to energy saving.

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